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Of course Pinkie Pie keeps a secret stash of chocolate in her hair. Because Pinkie Pie. :)

safe2176476 screencap295936 pinkie pie256108 equestria girls256177 equestria girls series40594 g42031087 the craft of cookies147 spoiler:eqg series (season 2)17258 apron5798 bowl2412 chocolate4595 clothes635417 curtains4031 cute266048 diapinkes12617 female1805012 food101430 grin63062 kitchen2826 plant3449 ponk1282 smiling398052 window14040
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KozumoJi
A Really Classy Artist - 250+ images under their artist tag
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Son of the Young Master
As chocolate is a natural diuretic (urine inducer) and stimulant, an overdose of chocolate can cause dehydration and rapid heartbeat (possibly leading to cardiac arrest)
 
The maximum amount of chocolate required to kill an average human being is 1000 milligrams per kilogram of body weight (the equivalent of 85 regular-sized Hershey bars)